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Investigating the fate of chemicals in the environment – Gabriel Sigmund, Wageningen University & Research

Investigating the fate of chemicals in the environment – Gabriel Sigmund, Wageningen University & Research

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On this episode I speak with Gabriel Sigmund, Assistant Professor at Wageningen University and Research, and board member of the International Panel on Chemical Pollution (IPCP).

We discuss:

  • Gabriel’s background and research interests
  • How the fate of charged organic compounds differs from neutral compounds
  • The issue of mobility in the environment and the concern around persistent, mobile and toxic (PMT) substances
  • Complex interactions controlling sorption and other fate processes in soil
  • The ongoing importance of laboratory experiments in the age of AI
  • Data availability and data quality challenges for persistence and mobility assessments
  • Implications of the new PMT/vPvM hazard classes under the EU CLP regulation
  • Simplification and essential use concepts for chemicals management
  • The issue of extreme persistence and the concern around trifluoroacetic acid (TFA)
  • Pesticides as a potential source of TFA to the environment
  • How differences in worldviews influences the debate on chemicals
  • Activities of the SETAC Persistence Science Interest Group


Apologies for some sound issues on this one.


Correction: During the discussion on TFA I commented that I had seen evidence in a presentation by Freeling that concentrations in plant samples had apparently increased four-fold between 2010 and 2020. Having revisited the published work (link below), the approximately four-fold increase was reported over the observation period 1989-2020.

Sorption and Mobility of Charged Organic Compounds: How to Confront and Overcome Limitations in Their Assessment | Environmental Science & Technology

The Global Threat from the Irreversible Accumulation of Trifluoroacetic Acid (TFA) | Environmental Science & Technology

Pesticides can be a substantial source of trifluoroacetate (TFA) to water resources - ScienceDirect

‘Alarming’ increase in levels of forever chemical TFA found in European wines | Pfas | The Guardian

Levels and Temporal Trends of Trifluoroacetate (TFA) in Archived Plants: Evidence for Increasing Emissions of Gaseous TFA Precursors over the Last Decades | Environmental Science & Technology Letters

Pollution is Colonialism - book by Max Liboiron (2021)

SETAC Persistence Science Interest Group

Webinar recording: Addressing Extreme Persistence – Identification, Behavior and Management of “Forever Chemicals” Beyond PFAS

Upcoming webinar: How to increase understanding of microbial inocula in biodegradation testing?

SETAC Europe 35th Annual Meeting

In Memoriam: John Parsons

Themed collection: Transformation Products and Mixtures – Environmental Science: Processes & Impacts

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